Graphene network enabled high speed electrical actuation of shape memory nanocomposite based on poly(vinyl acetate)

Here strong electroactive shape memory nanocomposites were prepared by incorporating graphene nanoplatelets into poly(vinyl acetate) (PVAc ) through the simple solvent mixing method. TEM and XRD revealed that well exfoliated graphene nanoplatelets formed a continuous network throughout the matrix with a large amount of interconnectedness. Dynamic mechanical analysis showed that the inclusion of graphene significantly improves both glassy and rubbery moduli of the matrix. Furthermore, the prepared nanocomposites demonstrated a marked electrical conductivity up to 24.7 S m^?1 and thereby surprisingly rapid electrical actuation behaviour exhibiting a 100% recovery ratio in 2.5 s. Moreover, PVAc and its nanocomposites displayed scratch self‐healing capability. This work demonstrates that the PVAc /graphene nanocomposites with high modulus and excellent electroactive shape memory performance can be a promising material in many applications such as sensors and fast deployable and actuating devices. © 2016 Society of Chemical Industry     

Superior Tribological Properties of Particulate Aluminum Matrix Nano Composites

Aluminum is the best metal for producing metal matrix composites which are known as one of the most useful and high-tech composites in our world. Combining aluminum and nano Al₂O₃ particles will yield a material with high mechanical properties. Characterization of tribological properties revealed that the presence of nano particles significantly increased wear resistance of the composite. In case of unreinforced Al alloy, the depth of penetration is governed by the hardness of the specimen surface and applied load. But, in case of Al matrix composite, the depth of penetration of the harder asperities of hardened steel disk is primarily governed by the protruded hard ceramic reinforcement. The hard Al₂O₃ particles act as a protrusion over the matrix, carries a major portion of the applied load and protect the abrasives from penetration into the specimen surface.     

Energy use efficiency and economical analysis of almond production: a case study in Chaharmahal-Va-Bakhtiari province,Iran

The aim of this study was to analyse input–output energy and economical assessment of almond production in three age groups of orchards (group I 6–10, group II 11–15 and group III 16–20 years old) in Chahrmahal-Va-Bakhtiari province, Iran. Data for almond production were collected by administering questionnaire in face-to-face interviews from the orchards selected based on random sampling method during a 3-year period. The results showed that 57,027.13, 60,341.14 and 61,640.43 MJ ha^?1 energy was consumed by group I, group II and group III, respectively. The most energy input was consumed by electricity, followed by chemical fertilizer. Energy indices were calculated, and the results revealed that energy efficiency was 0.62, 1.12 and 0.81 in the triple groups of orchards, respectively. Economical assessment showed that total production cost of almond in group I, II and III was $4547.54, $5799.26 and $5687.05 ha^?1, respectively. In all orchard groups, the shares of variable and fixed production costs found to be same nearly. Net return for almond production was $14,516.22, $30,735.19 and $21,395.57ha^?1, respectively. According to the research results, it was concluded that although almond production in the study region was not an efficient process in terms of energy consumption, it was a profitable agricultural operation.     

Optimizing the mechanical and physical properties of thermoplastic starch via tuning the molecular microstructure through co‐plasticization by sorbitol and glycerol

Nowadays, environmental hazards caused by plastic wastes are a major concern in academia and industry. Utilization of biodegradable polymers derived from renewable sources for replacing common petroleum‐based plastics is a potential solution for reducing the problem. In this regard, starch has become one of the most promising alternatives to non‐biodegradable polymers for depleting plastic waste thanks to its low expense, abundance, renewability and biodegradability. However, the main drawbacks of starch are its poor processability, weak mechanical properties and severe hydrophilicity. In this work, thermoplastic starch (TPS) samples have been prepared using glycerol and sorbitol as co‐plasticizers in a laboratory co‐rotating twin screw extruder. Based on the mechanical test results, glycerol caused higher elongation to break but had lower tensile strength and elastic modulus compared to sorbitol plasticized starch. Fourier transform infrared spectroscopy and DSC results indicated that the hydrogen bond interaction between starch chains and plasticizers could be improved by replacing glycerol by sorbitol, which resulted in higher resistance against retrogradation proved by XRD results. TGA illustrated that the higher the sorbitol to glycerol ratio was, the more stable was the TPS. Using a proper amount of plasticizers (42 wt% total plasticizer, sorbitol to glycerol ratio 2:1) led to the preparation of a TPS sample with optimized properties including enhanced mechanical properties, high thermal stability, strong hydrogen bond formation and high resistance against retrogradation. © 2017 Society of Chemical Industry     

CuIns2/Cus Nanocomposite: Synthesis via Simple Microwave Approach and Investigation Its Behavior in Solar Cell

CuInS₂/CuS nanocomposite were synthesized by a copper complex, [bis(ethylenediamine)copper(ΙΙ)] sulfate. Eight sulfur sources were used for this experiment. The products were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray analysis spectroscopy, and room temperature photoluminescence spectroscopy. Thin film of nanocomposite powder was fabricated and its feature (V_oc, J_sc and FF) was calculated by current–voltage (I–V) curve.     

Two-phase flow component fraction measurement using gamma-ray attenuation technique

Multiphase flow meters as the potential alternatives to separation and metering techniques have been in rapid development since 1980 s.Before its field operation,the instrument should be calibrated in a standard test-facility.In spite of the known medium and large scale facilities all over the world,we developed a laboratory scale instrument for component fraction measurements.It has a two-phase flow homogenizer loop with the clamp-on potential of the meters to provide a regime independent measurement.It is capable of delivering a complete homogenization by γ-ray densitometer.With an error of±5%in component fraction measurements,this instrument is appropriate for testing and calibrating other meters.     

Improvement of Grain Size and Dome Height of Microalloyed Steels Using Taguchi Method Based on Grey Relational Grade in Controlled Rolling

An efficient approach was introduced for improving the condition of major controlled rolling process parameters of roughing, finishing and coiling temperatures and optimizing these parameters to obtain minimum grain size and maximum dome height simultaneously. Taguchi method combined with grey relational analysis was applied to achieve optimum grain size and dome height during controlled rolling process. For this purpose, four levels for the above temperatures were chosen and sixteen experiments were conducted based on orthogonal array of Taguchi method. Based on Taguchi approach, signal-to-noise (S/N) ratios were calculated and used in order to obtain the optimum levels for every input parameter. Analysis of variance revealed that finishing and coiling temperatures have the maximum effect on the grain size and dome height of microalloyed steels. The confirmation tests with the optimal levels of parameters indicated that the grain size and dome height of controlled rolled microalloyed steels can be improved effectively through this approach.